Tsuji-Trost reaction

短语

词形变化

Tsuji-Trost reactions 复数 Tsuji-Trost reactions

释义与例句

n.
  1. 1.

    A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product.

    化学

词源

Pioneered by Jiro Tsuji in 1965 and later adapted by Barry Trost in 1973 with the introduction of phosphine ligands.

来源：wiktionary